Magnetic properties of nickel electrodeposited on porous GaN substrates with infiltrated and laminated connectivity
Abstract
We studied the magnetic properties of ferromagnetic-semiconductor composites based on nickel and porous-GaN, motivated by the effort to couple magnetic and semiconductor functionality. Nickel-infiltrated and nickel-coated (laminated thin-film) porous GaN structures were fabricated by electrodeposition, and their magnetic properties were subsequently examined collectively, by vibrating sample magnetometry and on the nanoscale, by magnetic force microscopy. We successfully demonstrated the ability to realize nickel infiltrated porous GaN, where the magnetic properties were dominated by the infiltrated material without a measurable surface contribution. We found that the structure and magnetization of electrodeposited porous-GaN/Ni composites depended on GaN degree of porosity and the amount of deposited nickel. The magnetization evolves from a nearly isotropic response in the infiltrated structures, to a shape-anisotropy controlled magnetic thin-film behavior. Furthermore, both infiltrated and thin-film nickel electrodeposited on porous GaN were found to have low (< 0.1%) strain and corresponding low coercivity: < 6.4 and < 2.4 kA/m for infiltrated and thin-film, correspondingly. An unconventional trend of increased remanence at room temperature, compared to cryogenic temperature, was observed in the thin film. The most likely cause for these findings is increased compliance of the porous GaN compared to bulk, allowing strain relaxation at room temperature. These results encourage deeper investigation of magnetic nanostructure property tuning and of magnetic property coupling to GaN and similar materials.
- Publication:
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Journal of Magnetism and Magnetic Materials
- Pub Date:
- August 2023
- DOI:
- 10.1016/j.jmmm.2023.170877
- arXiv:
- arXiv:2102.02904
- Bibcode:
- 2023JMMM..58070877G
- Keywords:
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- GaN;
- Nanoporous;
- Magnetic materials;
- MFM;
- Condensed Matter - Materials Science;
- Condensed Matter - Mesoscale and Nanoscale Physics
- E-Print:
- Supplamentary information included