Role of disorder in electronic and magnetic properties of Ag3LiIr2O6

The nature of magnetism in the intercalated honeycomb iridate Ag₃LiIr₂O₆ has been a subject of recent intensive debate, where the absence or presence of antiferromagnetic order has been reported to be related to possible structural disorder effects and an enhanced Ir-O hybridization and itinerancy with respect to the parent α -Li₂IrO₃ has been suggested as the origin of distinct x-ray spectroscopy features. In the present work we investigate the microscopic nature of the electronic and magnetic properties of Ag₃LiIr₂O₆ via a combination of density functional theory combined with exact diagonalization of ab initio derived models for various experimental and theoretical structures. We evaluate two possible scenarios, the itinerant quasimolecular framework (QMO) on the one hand, and the localized relativistic j_eff=1 /2 and j_eff=3 /2 picture on the other hand, and find that the second description is still viable for this system. We further calculate resonant inelastic x-ray scattering spectra and show that agreement with experimental observations can be obtained if the presence of Ag vacancies leading to changes in Ir filling and structural disorder is assumed. Finally, we show that the experimentally observed antiferromagnetic spiral magnetic order is reproduced by our ab initio derived magnetic models.