High-accuracy optical clocks based on group-16-like highly charged ions

We identify laser-accessible transitions in group-16-like highly charged ions as candidates for high-accuracy optical clocks, including S-, Se-, and Te-like systems. For this class of ions, the ground ^P3_J fine-structure manifold exhibits irregular (nonmonotonic in J ) energy ordering for large enough ionization degree. We consider the |^P3₂»⟷|^P3₀» (ground to first-excited state) electric quadrupole transition, performing relativistic many-body calculations of several atomic properties important for optical clock development. All ions discussed are suitable for production in small-scale ion sources and lend themselves to sympathetic cooling and quantum-logic readout with singly charged ions.