Accurate Einstein coefficients for electric dipole transitions in the first negative band of N2+
Abstract
Context. The N2+ fluorescence spectrum of comet C/2016 R2 is modelled in a companion paper. That work relies on accurate Einstein coefficients for electric dipole transitions between the B2∑u+ and X2∑g+ electronic states of N2+.
Aims: These coefficients are provided in the present paper.
Methods: The potential energy curves and transition dipole moments were computed at a high level of ab initio theory and include relativistic corrections. Rovibrational wavefunctions were then obtained without assuming separability of vibrational and rotational motions.
Results: Vibrationally and rotationally resolved Einstein coefficients are presented in a convenient three-parameter functional form for three isotopologues. A possible explanation is given for the large variation in the experimental radiative lifetimes.
- Publication:
-
Astronomy and Astrophysics
- Pub Date:
- May 2022
- DOI:
- 10.1051/0004-6361/202142869
- Bibcode:
- 2022A&A...661A.132F
- Keywords:
-
- radiative transfer;
- comets: general;
- molecular data;
- planets and satellites: atmospheres