Attosecond electronic and nuclear quantum photodynamics of ozone
Abstract
In the last few years we reported a series of numerical simulations proving that it is possible to create an electronic wave packet and subsequent electronic motion in a neutral molecule photoexcited by a UV pump pulse within a few femtoseconds. The ozone molecule has been served as sample system. By using extreme ultraviolet probe pulse the splitting of the excited B state nuclear wavepacket were followed into a path leading to molecular fragmentation and an oscillating path, revolving around the Franck-Condon point with 22-fs wave packet revival time. Recent experiment was strongly corroborated with our full quantum-mechanical ab initio simulations.
EU-funded Hungarian Grant EFOP-3.6.2-16-2017-00005.- Publication:
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APS Division of Atomic, Molecular and Optical Physics Meeting Abstracts
- Pub Date:
- 2020
- Bibcode:
- 2020APS..DMPD04007H