Thermodynamics and activity coefficients at infinite dilution for organic compounds in the ionic liquid 1-hexyl-3-methylimidazolium chloride
Abstract
Measurements of activity coefficients at infinite dilution using GLC. The (gas-liquid) partition coefficients were calculated. The excess thermodynamic functions, entropies, and Gibbs energies were calculated. The solubility parameter of the IL [HMIM][Cl] was determined. Selectivity and capacity for hexane (i)/benzene (j), cyclohexane (i)/benzene (j).
- Publication:
-
Journal of Chemical Thermodynamics
- Pub Date:
- January 2019
- DOI:
- Bibcode:
- 2019JChTh.128..187Z
- Keywords:
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- Activity coefficient at infinite dilution;
- Ionic liquid1-hexyl-3-methylimidazolium chloride [HMIM][Cl];
- Solubility parameter;
- Selectivity;
- Capacity;
- Separation