Determining the Parameters of Tetrahedral Splittings in the A 1- and A 2-Type States of Molecules with Spherical Symmetry ( T d or O h )
Abstract
A method of analytical description of one of the most complex problems in the study of high symmetry quantum-mechanical objects, namely, tetrahedral splittings, is considered. Results are presented that allow tetrahedral splittings of the vibrational states of A 1 and A 2 symmetries for polyad N ≤ 4 to be determined in an analytical form.
- Publication:
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Russian Physics Journal
- Pub Date:
- February 2018
- DOI:
- 10.1007/s11182-018-1269-x
- Bibcode:
- 2018RuPhJ..60.1684R
- Keywords:
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- molecules of tetrahedral symmetry;
- rovibrational spectrum;
- symmetrized operators;
- spectroscopic parameters