Chiral-crystal-structure transformations and magnetic states of R3Rh4Sn13 (R =La and Ce)
Abstract
Structural studies were performed on R3Rh4Sn13 (R =La and Ce). X-ray diffraction measurements on single-crystalline samples of both Rh-based compounds, which were synthesized by the molten Sn-flux method, have revealed structural transformations below TD≃ 350 K. The low-temperature superstructures are characterized by the wave vector q =(1 /2 ,1 /2 ,0 ) . The space group in the low-temperature phases of both compounds is chiral cubic I 213 , which is the same as that of R3Co4Sn13 (R =La and Ce). Neutron diffraction measurement of Ce3Rh4Sn13 revealed no magnetic long-range order below the temperature of the specific-heat peaks at 1.2 and 1.8 K. The low-temperature magnetic state in the chiral phase is that of a paramagnetic semimetal, whereas the dynamical spin correlation of Ce is deduced from the specific-heat data, as found previously in Ce3Co4Sn13 .
- Publication:
-
Physical Review B
- Pub Date:
- June 2018
- DOI:
- 10.1103/PhysRevB.97.235138
- Bibcode:
- 2018PhRvB..97w5138S