Describing screening in dense ionic fluids with a charge-frustrated Ising model
Abstract
Charge correlations in dense ionic fluids give rise to novel effects such as long-range screening and colloidal stabilization which are not predicted by the classic Debye-Hückel theory. We show that a Coulomb or charge-frustrated Ising model, which accounts for both long-range Coulomb and short-range molecular interactions, simply describes some of these ionic correlations. In particular, we obtain, at a mean field level and in simulations, a non-monotonic dependence of the screening length on the temperature. Using a combination of simulations and mean field theories, we study how the correlations in the various regimes are affected by the strength of the short ranged interactions.
- Publication:
-
Journal of Chemical Physics
- Pub Date:
- October 2018
- DOI:
- 10.1063/1.5043410
- arXiv:
- arXiv:1810.00918
- Bibcode:
- 2018JChPh.149p4505L
- Keywords:
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- Condensed Matter - Soft Condensed Matter;
- Condensed Matter - Statistical Mechanics
- E-Print:
- 8 pages, 6 figures