Visible-light-driven photocatalytic performance of nanohybrid incorporating nickel ions into the tetratitanate interlayer
Abstract
Ni-intercalated tetratitanate with a Ni:Ti molar ratio of 1:6.3 was prepared by electrostatically-driven self-assembly of the negatively charged exfoliated nanosheets and the positively charged nickel ions. The introduction of Ni2+ makes the doped titanate to possess spectral responses to visible light, contributed by the hybridization of the 3d orbits of Ni and Ti in the conduction band. The as-prepared materials exhibit mesoporous textures with expanded specific surface areas of more than 90 m2/g and highly photocatalytic activities in the degradation of methylene blue under visible-light irradiation.
- Publication:
-
Vacuum
- Pub Date:
- April 2017
- DOI:
- 10.1016/j.vacuum.2017.01.024
- Bibcode:
- 2017Vacuu.138...64H
- Keywords:
-
- Titanate;
- Dopant;
- Nickel;
- Intercalation materials;
- Photocatalysts