Magnetoelectric interaction and transport behaviours in magnetic nanocomposite thermoelectric materials

How to suppress the performance deterioration of thermoelectric materials in the intrinsic excitation region remains a key challenge. The magnetic transition of permanent magnet nanoparticles from ferromagnetism to paramagnetism provides an effective approach to finding the solution to this challenge. Here, we have designed and prepared magnetic nanocomposite thermoelectric materials consisting of BaFe₁₂O₁₉ nanoparticles and Ba_0.3In_0.3Co₄Sb₁₂ matrix. It was found that the electrical transport behaviours of the nanocomposites are controlled by the magnetic transition of BaFe₁₂O₁₉ nanoparticles from ferromagnetism to paramagnetism. BaFe₁₂O₁₉ nanoparticles trap electrons below the Curie temperature (T_C) and release the trapped electrons above the T_C, playing an 'electron repository' role in maintaining high figure of merit ZT. BaFe₁₂O₁₉ nanoparticles produce two types of magnetoelectric effect—electron spiral motion and magnon-drag thermopower—as well as enhancing phonon scattering. Our work demonstrates that the performance deterioration of thermoelectric materials in the intrinsic excitation region can be suppressed through the magnetic transition of permanent magnet nanoparticles.