Paleohydrology of the Polar Urals from the Last Glacial Maximum Through the Holocene

Paleohydrologic records provide important information concerning the past response of local hydrology to abrupt temperature changes. Arctic hydrology is particularly sensitive to temperature due to feedbacks involving sea ice and ice sheets. The most recent deglacial interval contains multiple abrupt temperature changes, which provide opportunities to study the relationship between temperature, ice sheets, and hydrology. We present a lacustrine δ2Hwax record from Bolshoye Schuchye, in the Polar Ural Mountains, spanning 24.5- 1.3 ka, and interpret hydroclimate conditions at a multi-centennial scale from the Last Glacial Maximum (LGM) through the Holocene. Bolshoye Schuchye's position beyond the reach of local glaciers during the LGM makes it a unique site, since lacustrine paleoclimate records from the Arctic rarely span this entire interval, so Bolshoye Schuchye helps to cover a gap in understanding of paleoclimate. Compound specific analysis of leaf wax hydrogen isotopes (δ2Hwax) is a hydroclimate proxy that can be used to infer moisture source area, transport history, and local aridity. Inferences based on δ2Hwax rely on mechanistic understanding of the process by which hydrogen from meteoric water is incorporated into waxes, and subsequently deposited in lake sediments. The δ2Hwax value of a sample reflects the isotopic composition of precipitation, while also incorporating fractionation that occurs between precipitation and uptake by plants, and biosynthetic fractionation during wax synthesis. Comparisons between different chain length waxes can be used to infer the isotopic composition of terrestrial and aquatic waxes, as terrestrial plants tend to produce longer chain lengths than aquatic macrophytes. The offset between terrestrial and aquatic δ2Hwax, expressed as ɛt-a, indicates differences between the precipitation used by terrestrial plants, and the lake water used by aquatic plants. Significant changes in ɛt-a can represent shifts in local aridity or precipitation seasonality. The record we present from Bolshoye Schuchye gives insights into terrestrial hydrologic changes resulting from rapid temperature shifts since the LGM.