Atmospheric Depositions of Natural and Anthropogenic Aerosols on the Guliya Ice Cap (Northwestern Tibetan Plateau) during the last 340 years
Abstract
Anthropogenic emissions (e.g., greenhouse gases, trace elements (TE) including toxic metals) to the atmosphere have dramatically increased since the Industrial Revolution in the 19th century. High temperature processes such as fossil fuel combustion and pyrometallurgy generate fumes and fine particles (< 0.1µm - 10 µm) containing toxic metals (e.g., Cd, Zn, Pb) that if not captured by emission controls can be transported over long distances by air masses and subsequently deposited far from their emission sources. Atmospheric TE monitoring programs, along with emission inventories, have been conducted in recent decades. However, they lack pre-1900 information which is necessary to contextualize current atmospheric changes. Thus, it is necessary to use natural archives (e.g., ice cores, lake sediments) to reconstruct atmospheric pollution trends. Glaciers and ice sheets preserve atmospheric species that are deposited as snow accumulates over time, creating valuable records of past climatic/environmental conditions. Polar ice cores have been used to obtain TE records. However, only a few non-polar ice core records provide continuous information back to pre-industrial times. Thus, ice core records of TEs from mid- and low-latitudes are needed to assess the spatial and temporal extent and levels of pollution in the environment. Here we present records of 29 TEs spanning the period 1650-1991 CE from the Guliya ice cap in the western Kunlun Mountains, northwest Tibetan Plateau to assess their natural and anthropogenic sources. The Guliya TEs records show two distinct periods with only crustal contributions prior to the 1850s and non-crustal contributions (Pb, Cd, Sb, Zn, Sn) after the 1850s. Enrichments of Pb, Cd, Sb, and Zn in Guliya between 1850 and 1950 can be attributed primarily to coal combustion emissions from western countries (Europe) while regional emissions (fossil fuel combustion, mining/smelting, fertilizers) from Central Asia, and probably from Kashgar in western China, and South Asia (India, Nepal) could be the source of the TE enrichments (Cd, Pb, Sn) observed in Guliya after 1950. This information can be used by modelers to assess pollution transport at local, regional, and global scales and by policy makers to develop strategies and policies to reduce their emissions.
- Publication:
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AGU Fall Meeting Abstracts
- Pub Date:
- December 2017
- Bibcode:
- 2017AGUFM.A13O..05S
- Keywords:
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- 0305 Aerosols and particles;
- ATMOSPHERIC COMPOSITION AND STRUCTURE;
- 0365 Troposphere: composition and chemistry;
- ATMOSPHERIC COMPOSITION AND STRUCTURE;
- 0736 Snow;
- CRYOSPHERE;
- 0750 Sea ice;
- CRYOSPHERE