New Model of the night-time CO2 4.3 µm emissions in the mesosphere/lower thermosphere
Abstract
We present a new non-LTE model of the night-time CO2 4.3 µm emissions in the MLT which accounts for various mechanisms of the non-thermal excitation of CO2 molecules. We pay specific attention to the transfer of vibrational energy of OH(v), produced in the chemical reaction H + O3, to the CO2(v3) vibrational mode. Two energy transfer channels are studied: 1) the "direct" mechanism, OH(v)→N2(v)→CO2(v3)→4.3 µm, suggested by Kumer et al, [1978], and 2) the new "indirect" mechanism, OH(v)→O(1D)→N2(v)→CO2(ν3)→4.3 µm, recently suggested by Sharma et al. [2015]. We show that for various seasonal scenarios above 75 km, the "direct" mechanism alone under-predicts the observed radiance between 30-70%, from 60°S-80°N. However, considering both the "direct" and "indirect" mechanism brings differences between simulated and measured nighttime SABER 4.3 µm limb radiances down to ±10% from 75-85 km and ±20% from 85-110km for the same region. These results suggest that the important mechanism of the nighttime 4.3 µm emission generation, which was missing in previous models [Lopez-Puertas and Taylor, 2001, Lopez-Puertas et al, 2004], has finally been found. This is an important step towards developing the algorithm suitable for retrieving CO2 densities in the MLT from nighttime limb radiances obtained by SABER, which has been taking continuous measurements for the past 15 years.
- Publication:
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AGU Fall Meeting Abstracts
- Pub Date:
- December 2016
- Bibcode:
- 2016AGUFMSA51A2412P
- Keywords:
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- 0305 Aerosols and particles;
- ATMOSPHERIC COMPOSITION AND STRUCTUREDE: 0340 Middle atmosphere: composition and chemistry;
- ATMOSPHERIC COMPOSITION AND STRUCTUREDE: 3303 Balanced dynamical models;
- ATMOSPHERIC PROCESSESDE: 3332 Mesospheric dynamics;
- ATMOSPHERIC PROCESSES