A New Approach for in-situ Determination of Pressure and Temperature in Multi-Anvil High Pressure Apparatus: Application to the Study of Elasticity of Hafnium
Abstract
In this study, we developed a new method for in-situ pressure determination in multi-anvil, high-pressure apparatus using an acoustic travel time approach within the framework of acoustoelasticity. The ultrasonic travel times of polycrystalline Al2O3 were calibrated against the NaCl pressure scale up to 15GPa and 1173K in a Kawai-type double-stage multi-anvil apparatus in conjunction with synchrotron X-radiation, thereby providing a convenient and reliable gauge for pressure determination at ambient and high temperatures. The pressures derived from this new travel time method are in excellent agreement with those from the fixed-point methods. Application of this new pressure gauge in an offline experiment revealed a remarkable agreement of the densities of coesite with those from the previous single crystal compression studies under hydrostatic conditions, thus providing strong validation for the current travel time pressure scale. The travel time approach not only can be used for continuous in-situ pressure determination at room temperature, high temperatures, during compression and decompression, but also bears a unique capability that none of the previous scales can deliver, i.e., simultaneous pressure and temperature determination with a high accuracy (±0.16GPa in pressure and ±17K in temperature). This new experimental capability is illustrated by our recent study on the elasticity of hafnium metal to 10 GPa. Therefore, the new in-situ Al2O3 pressure gauge is expected to enable new and expanded opportunities for offline laboratory studies of solid and liquid materials under high pressure and high temperature in multi-anvil apparatus.
- Publication:
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AGU Fall Meeting Abstracts
- Pub Date:
- December 2016
- Bibcode:
- 2016AGUFMMR12A..03Q
- Keywords:
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- 3909 Elasticity and anelasticity;
- MINERAL PHYSICSDE: 3954 X-ray;
- neutron;
- and electron spectroscopy and diffraction;
- MINERAL PHYSICSDE: 3620 Mineral and crystal chemistry;
- MINERALOGY AND PETROLOGYDE: 3694 Instruments and techniques;
- MINERALOGY AND PETROLOGY