The B2Π-X2Π electronic origin band of 13C6H
Abstract
The rotationally resolved spectrum of the B2Π-X2Π electronic origin band transition of 13C6H is presented. The spectrum is recorded using cavity ring-down spectroscopy in combination with supersonic plasma jets by discharging a 13C2H2/He/Ar gas mixture. A detailed analysis of more than a hundred fully-resolved transitions allows for an accurate determination of the spectroscopic parameters for both the ground and electronically excited state of 13C6H.
- Publication:
-
Journal of Molecular Spectroscopy
- Pub Date:
- February 2015
- DOI:
- 10.1016/j.jms.2015.01.005
- arXiv:
- arXiv:1501.03671
- Bibcode:
- 2015JMoSp.308...41B
- Keywords:
-
- Hexatriynyl radical;
- Cavity ring-down spectroscopy;
- Isotopic substitution;
- Supersonic plasma discharge;
- Physics - Atomic Physics
- E-Print:
- 4 pages, 1 figure, 2 tables
