Molecular Clouds in the Milky Way

In the past twenty years, the reconnaissance of ¹²CO and ¹³CO emission in the Milky Way by single-dish millimeter-wave telescopes has expanded our view and understanding of interstellar molecular gas. We enumerate the major surveys of CO emission along the Galactic plane and summarize the various approaches that leverage these data to determine the large-scale distribution of molecular gas: its radial and vertical distributions, its concentration into clouds, and its relationship to spiral structure. The integrated properties of molecular clouds are compiled from catalogs derived from the CO surveys using uniform assumptions regarding the Galactic rotation curve, solar radius, and the CO-to-H₂ conversion factor. We discuss the radial variations of cloud surface brightness, the distributions of cloud mass and size, and scaling relations between velocity dispersion, cloud size, and surface density that affirm that the larger clouds are gravitationally bound. Measures of density structure and gas kinematics within nearby, well-resolved clouds are examined and attributed to the effects of magnetohydrodynamic turbulence. We review the arguments for short, intermediate, and long molecular lifetimes based on the observational record. The review concludes with questions that shall require further observational attention.