Influence of Organic Matter - Mineral Interfacial Reactions on Metal(loid) Speciation and Bioaccessibility
Abstract
Bioaccessibility of contaminant metals in geomedia is often measured on the basis of kinetic release to solution during in vitro reaction with biofluid simulants. We postulate that development of a predictive-mechanistic understanding of bioaccessibility requires knowledge of metal(loid) molecular speciation upon sample introduction, as well as its change over the course of the in vitro reaction. Our results - including data from batch, column, mesocosm and field studies pertaining to arsenic, lead, and zinc contaminated materials - indicate the strong influence of organic matter and associated biological activity on metal(loid) speciation in mine tailings and related model systems. Furthermore, presence/absence of organic matter during bioassays affects the kinetics of metal(loid) release into biofluid simulants through multiple mechanisms.
- Publication:
-
AGU Fall Meeting Abstracts
- Pub Date:
- December 2015
- Bibcode:
- 2015AGUFM.B33D0727C
- Keywords:
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- 0414 Biogeochemical cycles;
- processes;
- and modeling;
- BIOGEOSCIENCES;
- 0428 Carbon cycling;
- BIOGEOSCIENCES;
- 0439 Ecosystems;
- structure and dynamics;
- BIOGEOSCIENCES;
- 0486 Soils/pedology;
- BIOGEOSCIENCES