Experimental and theoretical studies of the reactions of chlorine atoms with 1,2-dichloroethane and 1,2-dichloroethane-d4 in the gas phase. The kinetics of hydrogen atom abstraction from the -CH2Cl group in chloroethane and 1,2-dichloroethane
Abstract
The rate constant for H-abstraction (kH) from CH2ClCH2Cl and D-abstraction (kD) from CD2ClCD2Cl by chlorine atoms is described by the expressions: kH = (1.99 ± 0.12) × 10-11 exp(-777 ± 23/T) cm3 molecule-1 s-1 and kD = (1.73 ± 0.12) × 10-11 exp(-1148 ± 16/T) cm3 molecule-1 s-1. The experiment revealed significant differences in the values of the rate constants for the abstraction of H-atom from the -CH2Cl group in chloroethane and 1,2-dichloroethane. The explanation of these differences was the subject of theoretical studies. The calculated potential energy barriers for the abstraction reaction confirmed the experimental results.
- Publication:
-
Chemical Physics Letters
- Pub Date:
- March 2014
- DOI:
- 10.1016/j.cplett.2014.02.026
- Bibcode:
- 2014CPL...597...86S