Sustainable Horizontal Bioventing and Vertical Biosparging Implementation (Invited)
Abstract
A former natural gas processing site with total petroleum hydrocarbons (TPH) and benzene, toluene, ethylbenzene, and xylene (BTEX) impacts in both soil and groundwater was partially excavated to remove 2,400 cubic yards of impacted soil. However, due to active natural gas pipelines within the impacted footprint, excavation was discontinued and an area of impacted soil containing maximum concentrations of 5,000 mg/kg gasoline-range organics (GRO), 8,600 mg/kg diesel-range organics (DRO), and 130 mg/kg motor oil-range organics (ORO). Groundwater was impacted with concentrations up to 2,300 μg/L GRO and 4,200 μg/L DRO remained in place. Taking advantage of the open excavation, horizontal-screened piping was placed in the backfill to deliver air for bioventing, which resulted in successful remediation of soil in a physically inaccessible area. The combined use of excavation of the source area, bioventing of surrounding inaccessible soil, and biosparging of the groundwater and smear zone resulted in nearing a no-further-action status at the site. The sustainable bioventing system consisted of one 3-HP blower and eight horizontal air injection wells. Five dual-depth nested vapor monitoring points (VMPs) were installed at 5 feet and 10 feet below ground surface as part of the monitoring system for human health and system performance. The bioventing system operated for one year followed by a three-month rebound test. During the one-year operation, air flow was periodically adjusted to maximize removal of volatile organic compounds (VOCs) from the vent wells with elevated photo-ionization detector readings. After the bioventing successfully remediated the inaccessible impacted soil, the biosparging system incorporated the pre-existing bioventing unit with an upgraded 5-HP blower and three vertical biosparging wells to biodegrade dissolved phase impacts in the groundwater. The subsequent monitoring system includes the VMPs, the air injection wells, and four groundwater monitoring wells including three existing wells. The system is scheduled to operate for at least one year followed by a three-month rebound test. The flow rate was adjusted between 5 and 10 scfm during operations to focus the biosparging in the impacted area of the site. After the bioventing system was operated and optimized for a year, average VOC concentrations were reduced from approximately 120 to 5 ppmv in the vadose zone. TPH gasoline and BTEX concentrations experienced reductions up to 99%. Fugitive VOCs were not detected outside the property boundary or at possible fugitive gas monitoring points. During the rebound test, no significant rebound of VOC concentrations was observed. The average hydrocarbon biodegradation rate was estimated to be approximately 2.5 mg TPH/kg soil/day. During biosparging, the migration of injected air also stimulated biodegradation in the vadose zone. Within six months of operation, the groundwater GRO and DRO concentrations decreased approximately 70% and 50%, respectively, at the monitoring well within the excavation/backfill area. Bioventing followed by biosparging has proven to be successful in decreasing soil vapor chemicals of concern in the native soil of the inaccessible area and in groundwater of the excavation/backfill area.
- Publication:
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AGU Fall Meeting Abstracts
- Pub Date:
- December 2013
- Bibcode:
- 2013AGUFM.H13C1332L
- Keywords:
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- 1831 HYDROLOGY Groundwater quality;
- 1875 HYDROLOGY Vadose zone