Analysis of CCN activity of Remote and Combustion Aerosol over the South East Pacific during autumn 2008 and links to Sc cloud properties
Abstract
The earth's most extensive Stratocumulus (Sc) deck, situated off the coast of Northern Chile and Southern Peru, strongly influences the radiation budget and climate over the South East Pacific (SEP) by enhancing solar reflection. This feature makes Sc clouds an important constituent for climate modeling, yet these clouds are poorly represented in models. A large uncertainty in understanding the variability in these low cloud fields arises from our deficit in understanding the role of aerosol. Hence, a major goal of the VOCALS (www.eol.ucar.edu/projects/vocals) campaign in 2008 was to further explore and assess interactions of natural and anthropogenic aerosol with Sc clouds in both the more polluted coastal environment and west of 80W where we encountered nearly pristine boundary layer clouds often exposed to cloud-top entrainment of pollution aerosol from the free troposphere. Extensive airborne measurements of size-resolved aerosol volatility and chemical composition collected aboard the NCAR C-130 were analyzed with an aerosol mass spectrometer (AMS) and a single particle soot photometer (SP2) to calculate aerosol hygroscopicity (κ) and predict cloud condensation nuclei (CCN) concentration for all observed air mass types above and below cloud utilizing estimated Sc cloud supersaturations deduced from cloud-processed aerosol size distribution information. The predicted CCN agree to within 10% to measured CCN. Results from this analysis are presented here and CCN variability observed along VOCALS flight tracks is discussed in conjunction with size-resolved cloud droplet information. This includes assessing the impact of aerosol perturbations on the shape of the cloud droplet size distribution parameterized in models and satellite algorithms such as cloud top effective radius retrievals. We will further discuss cloud droplet residual composition collected using a counterflow virtual impactor (CVI) and analyzed with the AMS and SP2. Size resolved variations in residual composition and its relation to CCN composition measured outside the cloud will be examined in terms of the influence of aerosol concentration, size, and chemical composition on Sc clouds.
- Publication:
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AGU Fall Meeting Abstracts
- Pub Date:
- December 2013
- Bibcode:
- 2013AGUFM.A43G0356F
- Keywords:
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- 0305 ATMOSPHERIC COMPOSITION AND STRUCTURE Aerosols and particles;
- 0320 ATMOSPHERIC COMPOSITION AND STRUCTURE Cloud physics and chemistry;
- 0345 ATMOSPHERIC COMPOSITION AND STRUCTURE Pollution: urban and regional;
- 0321 ATMOSPHERIC COMPOSITION AND STRUCTURE Cloud/radiation interaction