Synthesis and X-ray diffraction study of [UO2(NO3)2(H2O)2] · 2C12H18O
Abstract
The compound [UO2(NO3)2(H2O)2] · 2C12H18O was synthesized and studied by IR spectroscopy and X-ray diffraction. The structure consists of the neutral island groups [UO2(NO3)2(H2O)2], which belong to the crystal-chemical group AB 01 2 M 1 2 ( A = UO2 2+, B 01 = NO{3/-}, M 1 = H2O) of uranyl complexes, and 1-adamantyl methyl ketone molecules. The characteristic features of the association of the complexes [UO2(NO3)2(H2O)2] and 1-adamantyl methyl ketone molecules in the crystal structure via hydrogen bonds are considered with the use of Voronoi-Dirichlet polyhedra.
- Publication:
-
Crystallography Reports
- Pub Date:
- March 2012
- DOI:
- 10.1134/S1063774512020186
- Bibcode:
- 2012CryRp..57..252S