Chasing storms in an agricultural catchment: the stream DOM story

Storm events are notorious for mobilizing large amounts of dissolved and particulate substances in streams and rivers. Conversion of natural landscapes to agricultural land-use can significantly amplify this effect. We investigated the impacts of two storm events on stream dissolved organic matter (DOM) in 2008 in Willow Slough, a California/Sacramento Valley agricultural catchment. The tools utilized included carbon stable isotopes, fluorescence, ultraviolet-visible absorbance, lignin, disinfection byproduct formation potential, and biodegradation experiments. Dissolved organic carbon (DOC) concentrations at the mouth at peak discharge during the storms ranged from 9-10 mg/L compared to baseline conditions of 2-4 mg/L. Other storm effects included increased dissolved organic nitrogen, depleted carbon stable isotopes, increased humic fluorescence intensity, increased specific UV absorbance (SUVA), decreased spectral slopes, increased bioavailability, and increased carbon-normalized yields of lignin. Increased frequency and intensity of storms due to climate change are likely to have a non-linear effect on riverine exports and water quality, with subsequent impacts on carbon loading, mercury transport, and drinking water quality.