H2 molecule in strong magnetic fields
Abstract
The Pauli Hamiltonian of a molecule with fixed nuclei in a strong constant magnetic field is asymptotic, in norm-resolvent sense, to an effective Hamiltonian which has the form of a multi-particle Schrödinger operator with interactions given by one-dimensional δ-potentials. We study this effective Hamiltonian in the case of the H2 molecule and establish the existence of the ground state. We also show that the inter-nuclear equilibrium distance tends to 0 as the field strength tends to infinity.
- Publication:
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Journal of Physics A Mathematical General
- Pub Date:
- November 2010
- DOI:
- 10.1088/1751-8113/43/47/474005
- arXiv:
- arXiv:1208.2713
- Bibcode:
- 2010JPhA...43U4005B
- Keywords:
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- Mathematical Physics;
- Physics - Atomic Physics
- E-Print:
- Journal of Physics A: Mathematical and Theoretical 43 (2010) 474005