Structure and defects at the SiC:SiO2 interface
Abstract
The pervasion of defects at the SiC:SiO2 interface has limited the performance and commercializing of SiC based transistors. While the defects are believed to be related to excess carbon in the interfacial region, no compelling microscopic models exists. Here we report the generation of microscopic interfaces models for the SiC:SiO2 interface. These models include a 1 nm amorphous oxide and several layers of crystalline SiC. Defect and defect reactions are explored. For instance, the 3-fold bonded carbon defect is calculated to have an acceptor level at Ev + 1.4 eV close to the value found experimentally and encouraging confidence in the methods employed. The recently discovered beneficial effect of sodium ions motivates our examination of the basic electrochemistry of the sodium ion interactions with the ideal and defected interfaces. A comparison between microscopic defect results and experiment will be presented.
- Publication:
-
APS March Meeting Abstracts
- Pub Date:
- March 2010
- Bibcode:
- 2010APS..MARD25008T