Molecular orientation and mechanical anisotropy of polypropylene sheet containing N,N′‑dicyclohexyl‑2,6‑naphthalenedicarboxamide
Abstract
Effect of mixing and processing conditions at T‑die extrusion on the structure and mechanical properties is studied for isotactic polypropylene (PP) containing a small amount of β‑form nucleating agent, N,N′‑dicyclohexyl‑2,6‑naphthalenedicarboxamide. It is found that trigonal β crystals are predominantly formed in the extruded samples containing the nucleating agent irrespective of the mixing and processing conditions, leading to the marked mechanical toughness. On the contrary, the molecular orientation is significantly affected by the mixing and processing conditions. In particular, it should be noted that PP molecules in the extruded sheet which was mixed at high temperature (260 °C) and extruded at low temperature (200 °C) orient perpendicular to the applied flow direction. As a result, the sheet shows anomalous mechanical anisotropy.
- Publication:
-
Journal of Polymer Science B Polymer Physics
- Pub Date:
- February 2009
- DOI:
- 10.1002/polb.21647
- Bibcode:
- 2009JPoSB..47..424U