Importance of Chain Connectivity in the Formation of Non-covalent Interactions between Polymers and Single-Walled Carbon Nanotubes
Abstract
Our work is focused on understanding and utilizing non-covalent electron donor-acceptor (EDA) interactions between polymers and SWNT to optimize interfacial adhesion and homogeneity of nanocomposites without modifying the SWNT native surface. Nanocomposites with polymer bound electron donating 2-(dimethylamino)ethyl methacrylate or electron accepting acrylonitrile and cyanostyrene moieties leads to improved SWNT dispersion if the interacting functional group is a minor component of a copolymer matrix. Correlation of experimental (Raman mapping, Raman D* band peak shifts, and optical microscopy) and computational results indicates that chain connectivity is critical in controlling the accessibility of the functional groups to form EDA interactions. Thus, controlling the amount of e^- donating or withdrawing moieties throughout the polymer chain will direct the extent of EDA interaction, which enables tuning the SWNT dispersion.
- Publication:
-
APS March Meeting Abstracts
- Pub Date:
- March 2009
- Bibcode:
- 2009APS..MARA19006L