Restricted Open-Shell Kohn-Sham Theory IV: Expressions for N Unpaired Electrons
Abstract
We present an energy expression for restricted open-shell Kohn-Sham theory for N unpaired electrons and single-electron operators for all multiplets formed from up to five unpaired electrons. It is shown that it is possible to derive an explicit energy expression for all low-spin multiplets of systems that exhibit neither radial nor cylindrical symmetry.
- Publication:
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arXiv e-prints
- Pub Date:
- August 2008
- DOI:
- arXiv:
- arXiv:0808.1190
- Bibcode:
- 2008arXiv0808.1190S
- Keywords:
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- Physics - Chemical Physics
- E-Print:
- schulte.tar: tex-file and 7 figures (eps)