Electromagnetic transport properties and magnetoresistance of La 0.7Ca 0.2Sr 0.1MnO 3-Ag composites prepared by electroless process
Abstract
A series of bulk polycrystalline La 0.7Ca 0.2Sr 0.1MnO 3 (LCSMO)-Ag composites were prepared by electroless plating process and several kinds of physical properties have been studied systemically. According to the results of X-ray diffraction (XRD), scanning electron microscopy (SEM), and electromagnetic transport properties, we can see that Ag-added segregated at the surfaces or interfaces of LCSMO grains. The metal-insulator transition temperature ( TP) and Curie temperature ( Tc) were almost unchanged but ρ decreased with increasing plating time. We also observed Ag-added can significantly enhance the magnetoresistance (MR) near TP under a low applied field (3000 Oe) and the room temperature MR reached to 35% under 20 kOe, which is encouraging for practical applications. We can suggest that improved grain boundary effect by Ag-added is responsible for the enhancement.
- Publication:
-
Journal of Solid State Chemistry France
- Pub Date:
- September 2008
- DOI:
- 10.1016/j.jssc.2008.04.041
- Bibcode:
- 2008JSSCh.181.2123X
- Keywords:
-
- 75.47.Lx;
- 61.72.Mm;
- 75.60.Ch;
- Manganites;
- Grain and twin boundaries;
- Domain walls and domain structure