Spectroscopy Study (IR, 1HNMR, 13C-NMR, MS) of Methyl Cyanide Addition Compound of Boron Trichloride. Donor-Aceptor Bonding and Applications
Abstract
The 1:1 CH3 CN: BCl3 complex was prepared by reacting equimolecular quantities of CH3 CN and BCl3 and was characterized by IR, 1 H-NMR, 13C- NMR, mass spectroscopy and elemental analysis. High resolution electron microscopy (HRTEM) and electron energy loss spectroscopy (EELS) suggest that the stoichiometry of the filaments ca..[BC2N] obtained from pyrolysis of CH3-CN:BCl3.
- Publication:
-
Frontiers of Fundamental Physics
- Pub Date:
- April 2007
- DOI:
- 10.1063/1.2737009
- Bibcode:
- 2007AIPC..905..179M
- Keywords:
-
- 39.30.+w;
- 79.20.Uv;
- 61.50.Nw;
- 82.30.Lp;
- Spectroscopic techniques;
- Electron energy loss spectroscopy;
- Crystal stoichiometry;
- Decomposition reactions