Record of Hybridization Preserved in Zircon, Aztec Wash Pluton, NV

The mid-Miocene Aztec Wash pluton comprises a smaller granite zone and a larger, highly heterogeneous zone in which evidence for interaction between basaltic and granitic magmas is ubiquitous. Granitic rocks in both zones show textural and compositional evidence for crystal accumulation and melt fractionation. In the heterogeneous zone, basalts have chilled, crenulate margins against granitic rocks, and there is widespread evidence for mechanical contamination of each lithology (coarse resorbed alkali feldspar in fine-grained mafic rock; mafic enclaves in granite). "Grey rocks" of intermediate composition are exposed on dm to 100's of m-scale as enclaves, pods, and initially subhorizontal sheets. They are variable texturally, but most are dominantly fine- grained and equigranular. Textures of grey rocks are consistent with rapid solidification from melt-rich magma, and, in combination with isotopic compositions intermediate between felsic and mafic rocks of the pluton, suggest an origin by near-complete homogenization of a hybrid melt (Bleick et al. 2005; Ericksen 2005). The elemental chemistry of zircon preserves information about the evolving magmatic environment in which it was hosted (Claiborne et al., 2006). Owing to its slow dissolution rate, it has the potential to survive periods of undersaturation with only partial resorption. Thus, it may record drastic shifts in T and melt chemistry that would accompany mafic-felsic hybridization. We are investigating zircon zoning patterns by cathodoluminescence (CL) and elemental compositions by SHRIMP-RG to evaluate the record of processes that they preserve. Temperatures of zircon growth are estimated using Ti-in-zircon thermometry (Watson et al. 2006), assuming a(TiO2) of ca. 0.7 (sphene +/-ilmenite are ubiquitous). Zircons from the granite zone yield estimated T's of 700-860 C, whereas those from grey rocks range from 710- 910 C. While both granite and grey zircon populations show dramatic T variations among and within grains, fluctuation tends to be more common and extreme in grains from the grey rocks, where variations exceed 100°C. Such grains appear to have both survived and recorded a substantial heating event, as would be expected if either mixing or thorough mingling occurred. Zircons from the granitic samples almost invariably have euhedral, concentric, oscillatory zoning; some have truncations in zoning indicating resorption, and many have thin, CL-dark rims. Grey rock zircons typically display thick, concentric zoning or, less commonly, banding, are rarely oscillatory zoned, and many exhibit indistinct or anhedral internal zoning (corresponding to high calculated T). Many have thick CL-bright rims and resorbed surfaces. These rims apparently represent relatively cool (less than 800 C) late stage growth following the heating event recorded in grain interiors. In both granitic and grey samples, Hf (6500-13000 ppm) shows a strong negative correlation with calculated T. In all granite samples, U (100-3000 ppm) & Th (150-3500 ppm) concentrations likewise show a strong negative correlation with calculated T, indicating that both acted as incompatible elements in these magmas. U (50-2000 ppm) & Th (50-2000 ppm) compositions show equally dramatic, but far less systematic, variation in grey samples, with high concentrations at elevated T. Growth of "hot" U, Th-rich zircon at Aztec Wash appears to be limited to the mixing environment.