A proof of Jarzynski's nonequilibrium work theorem for dynamical systems that conserve the canonical distribution
Abstract
We present a derivation of the Jarzynski [Phys. Rev. Lett. 78, 2690 (1997)] identity and the Crooks [J. Stat. Phys. 90, 1481 (1998)] fluctuation theorem for systems governed by deterministic dynamics that conserves the canonical distribution such as Hamiltonian dynamics, Nosé-Hoover dynamics, Nosé-Hoover chains, and Gaussian isokinetic dynamics. The proof is based on a relation between the heat absorbed by the system during the nonequilibrium process and the Jacobian of the phase flow generated by the dynamics.
- Publication:
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Journal of Chemical Physics
- Pub Date:
- August 2006
- DOI:
- arXiv:
- arXiv:cond-mat/0603856
- Bibcode:
- 2006JChPh.125e4105S
- Keywords:
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- 05.70.Ln;
- 05.40.-a;
- Nonequilibrium and irreversible thermodynamics;
- Fluctuation phenomena random processes noise and Brownian motion;
- Condensed Matter - Statistical Mechanics
- E-Print:
- 12 pages