Phase behavior of short-range square-well model
Abstract
Various Monte Carlo techniques are used to determine the complete phase diagrams of the square-well model for the attractive ranges λ =1.15 and λ =1.25. The results for the latter case are in agreement with earlier Monte Carlo simulations for the fluid-fluid coexistence curve and yield new results for the liquidus-solidus lines. Our results for λ =1.15 are new. We find that the fluid-fluid critical point is metastable for both cases, with the case λ =1.25 being just below the threshold value for metastability. We compare our results with prior studies and with experimental results for the γII-crystallin.
- Publication:
-
Journal of Chemical Physics
- Pub Date:
- May 2005
- DOI:
- arXiv:
- arXiv:cond-mat/0412177
- Bibcode:
- 2005JChPh.122r4515P
- Keywords:
-
- 82.70.Dd;
- 64.70.Dv;
- 64.60.Fr;
- 64.60.My;
- Colloids;
- Solid-liquid transitions;
- Equilibrium properties near critical points critical exponents;
- Metastable phases;
- Statistical Mechanics
- E-Print:
- 8 figures, 1 table