Rate constants and branching ratios for the dissociative recombination of C3D7+ and C4D9+
Abstract
Product branching ratios and thermal rate coefficients for the dissociative recombination of C3D7+ and C4D9+ have been measured in the ion storage ring CRYRING. The results for C3D7+ are believed to be slightly more accurate than those obtained earlier for C3H7+. Only the C-C bond breaking channels could be measured for C4D9+ and were found to be in excellent agreement with earlier data.
- Publication:
-
Journal of Chemical Physics
- Pub Date:
- April 2005
- DOI:
- 10.1063/1.1872839
- Bibcode:
- 2005JChPh.122o6101L
- Keywords:
-
- 82.30.Lp;
- 82.30.Fi;
- 82.30.Nr;
- 82.20.Pm;
- 82.20.Tr;
- Decomposition reactions;
- Ion-molecule ion-ion and charge-transfer reactions;
- Association addition insertion cluster formation;
- Rate constants reaction cross sections and activation energies;
- Kinetic isotope effects including muonium