Luminescence and defects creation under photoexcitation of CsI : Tl crystals in Tl +-related absorption bands
Abstract
Characteristics of the defects created at 4.2 K by the UV-irradiation of CsI : Tl crystals in the Tl +-related absorption bands (by photons of 5.8–4.8 eV energy) have been studied. The dependences of the intensities of the thermally stimulated luminescence peaks appearing near 60, 90 and 125 K and of the recombination luminescence photostimulation bands peaking at 2.35, 1.92, 1.33 and 0.89 eV on the irradiation energy and duration, uniaxial stress and thallium concentration have been examined. The mechanisms of the processes, responsible for the appearance of the intense visible (2.55 and 2.25 eV) luminescence of excitons localized near Tl + ions and creation of defects pairs of the type of Tl 0–V K and Tl +–V K with various distances between the components, have been discussed.
- Publication:
-
Journal of Luminescence
- Pub Date:
- January 2002
- DOI:
- 10.1016/S0022-2313(01)00215-0
- Bibcode:
- 2002JLum...96...75B
- Keywords:
-
- 71.35.‑y;
- 71.55.‑i;
- 61.80.Ba;
- 78.55.‑m;
- 78.55.Fv;
- Exciton luminescence;
- Defects;
- Ultraviolet irradiation;
- CsI : Tl