Facile syntheses of tris(trifluoromethyl)phosphine and difluorotris (trifluoromethyl) phosphorane
Abstract
Tris(trifluoromethyl) phosphine is easily available in high yield using the three component system D(NAt) 2) 3/NF 3Ar/(DhI) 3D in IIDA. Addition of chlorine and fluorination with zinc difluoride yield difluorotris (trifluoromethyl) phosphorane.
- Publication:
-
Journal of Fluorine Chemistry
- Pub Date:
- January 1996
- DOI:
- 10.1016/0022-1139(96)03471-9
- Bibcode:
- 1996JFluC..79..103G
- Keywords:
-
- Tris(trifluoromethyl)phosphine;
- Hexaethylphosphorus triamide;
- Bromotrifluoromethane;
- Triphenylphosphite;
- Zinc difluoride;
- Difluorotris (trifluoromethyl) -phosphorane