Preparation and vibrational spectroscopy of di- n-butyl phosphate complexes of zirconium nitrate
Abstract
The vibrational spectra of the complexes Zr(NO 3) 2 (DBP) 2 and Zr(NO 3) 2(DBP) 2(HDBP) 4 have been characterised, with the provision of Raman spectroscopic data for the first time. Several inconsistencies in the literature for the infrared spectra of these compounds have been resolved and from Raman polarisation data the mode of coordination of the nitrato ligand in the Zr(NO 3) 2(DBP) 2(HDBP) 4 complex is suggested to be monodentate.
- Publication:
-
Journal of Molecular Structure
- Pub Date:
- June 1995
- DOI:
- 10.1016/0022-2860(94)08486-2
- Bibcode:
- 1995JMoSt.351...65E