Femtosecond transient stimulated emission pumping studies of ozone visible photodissociation
Abstract
We report a new variant of the femtosecond transition-state spectroscopy technique-transient stimulated emission pumping (TSEP). The initial application of TSEP to studies of ozone visible photodissociation indicates that the molecule is trapped in the Franck-Condon region for ∼90 fs. The wave packet then spreads along the reaction coordinate.
- Publication:
-
Journal of Chemical Physics
- Pub Date:
- August 1992
- DOI:
- 10.1063/1.463102
- Bibcode:
- 1992JChPh..97.2149C
- Keywords:
-
- Franck-Condon Principle;
- Ozone;
- Photodissociation;
- Potential Energy;
- Stimulated Emission;
- Wave Packets;
- Atmospheric Chemistry;
- Emission Spectra;
- Photoexcitation;
- Atomic and Molecular Physics