The clustering reactions of Na+ and Pb+ with several important ligands
Abstract
Enthalpy, Entropy, and Gibb's free energy changes for the clustering reactions of Na+ and Pb+ with several important atmospheric molecules and organic solvents have been measured by using high pressure mass spectrometry (HPMS). The unusually strong bonding has been found in Na+ ion complexes where ligands have large high moments and polarizabilities as well as in Pb+ ion complexes. The enhancement of the bonding by ion-high moment, ion-induced dipole, and dispersion interactions may account for the strong bonding in some of Na+ ion complex systems, while the strong bonding in Pb+ ion complexes may results from the hybridization of 6 s and 6 p orbitals of Pb+ ion.
- Publication:
-
Zeitschrift fur Physik D Atoms Molecules Clusters
- Pub Date:
- March 1991
- DOI:
- 10.1007/BF01448337
- Bibcode:
- 1991ZPhyD..19..397G
- Keywords:
-
- 36.40+d;
- 82.60