Viscosity of high-temperature iodine
Abstract
The viscosity coefficient of iodine in the temperature range 500<=T<=3000 K is calculated. Because of the low dissociation energy of the I2 molecules, the dissociation degree of the gas increases quickly with temperature, and I+I2 and I+I collisions must be taken into account in calculations of viscosity at temperatures greater than 1000°. Several possible channels for atom-atom interaction are considered, and the resulting collision integrals are averaged over all the important channels. It is also shown that the rigid-sphere model is inaccurate in predictions of the viscosity. The approach of the present work is general and can be used for other diatomic gases with arbitrary dissociation degree.
- Publication:
-
Physical Review A
- Pub Date:
- September 1991
- DOI:
- 10.1103/PhysRevA.44.3596
- Bibcode:
- 1991PhRvA..44.3596K
- Keywords:
-
- Atomic Interactions;
- Gas Flow;
- Iodine;
- Particle Collisions;
- Thermal Dissociation;
- Viscosity;
- Atomic Energy Levels;
- Binary Mixtures;
- Chapman-Enskog Theory;
- Vibrational Spectra;
- Thermodynamics and Statistical Physics;
- 51.30.+i;
- 52.20.Hv;
- 52.25.Fi;
- Thermodynamic properties equations of state;
- Atomic molecular ion and heavy-particle collisions;
- Transport properties