Photoelectron spectroscopy of IO(-)
Abstract
The IO(2Pi3/2,2Pi1/2;v-prime) + e(-) - IO(-)(1Sigma/+/;v-double prime) spectrum is obtained via photoelectron spectroscopy. The 351.1 nm photoelectron spectrum of IO(-) taken at the 'magic angle' is shown. Unknown molecular constants for IO(-) and IO are determined from Franck-Condon simulations of the spectrum for each of the electronic transitions observed.
- Publication:
-
Journal of Chemical Physics
- Pub Date:
- September 1991
- DOI:
- 10.1063/1.461746
- Bibcode:
- 1991JChPh..95.4723G
- Keywords:
-
- Electron Affinity;
- Electron Transitions;
- Energy Spectra;
- Franck-Condon Principle;
- Iodine Compounds;
- Photoelectron Spectroscopy;
- Ground State;
- Molecular Energy Levels;
- Quantum Chemistry;
- Spin-Orbit Interactions;
- Ultraviolet Radiation;
- Atomic and Molecular Physics