The compositional classification of chondrites: V. The Karoonda (CK) group of carbonaceous chondrites

Petrographie and bulk compositional data reveal the existence of a new group of carbonaceous chondrites consisting of the observed fall, Karoonda, one large find from Maralinga, Australia, and 6-11 small finds from five sites in Antarctica. Ningqiang, also a fall, is genetically related to the group. Compositional, textural, and O-isotope data show that the new group is closely related to CV and CO chondrites. In keeping with the practice of naming carbonaceous chondrite groups after a prominent member, we designate it the Karoonda or CK group. All normal CK members are metamorphosed; petrographie grades range from 4 to 6. Some contain shock veins and all exhibit various degrees of blackening due to the dispersion of fine particles of sulfides and magnetite in silicates. Only one other group (EL) has no unequilibrated members. The unequilibrated Ningqiang chondrite is more similar to CK than to CV or CO chondrites, but differs significantly (e.g., low refractory lithophiles, high Mn and Na) in detailed composition. Elemental abundance patterns in CK chondrites are similar to those in CO chondrites, and even more similar to those in CV chondrites. Refractory lithophile abundances are about 1.21× greater than in CI chondrites, a level intermediate between those in CO and CV chondrites; CK refractory siderophile abundances are also intermediate between CV and CO levels. The CK volatile abundance pattern is quite similar to the CV pattern, with CK abundances of most volatiles 10-20% lower than CV values. It appears that nebular conditions and processes were closely similar at the CK and CV formation locations. Although precise probability calculations are difficult because of uncertainties regarding pairing and because so few samples are known, the exceptional abundance of CK chondrites in Antarctica requires an explanation. We suggest that compared to other groups, such as CO or CV, the fragmentation of the CK parent object(s) produced a substantially larger proportion of small meteoroids.