Band oscillator strengths of the (2,1)-(12,1) Schumann-Runge bands of O2 from absolute absorption cross-section measurements at room temperature
Abstract
The absolute absorption cross sections of the (2,1)-(12,1) Schumann-Runge bands of O2 at room temperature have been obtained from measurements of the total absolute absorption cross section arising from transitions from the ground-state levels with v`=0 and 1 by subtraction of the v`=0 contributions, which have been synthesized from our previous determinations of the band oscillator strengths, line center positions and predissociation line widths of the (v',0) Schumann-Runge bands of O2. The resultant absolute absorption cross sections of the (2,1)-(12,1) bands have been integrated numerically to obtain the band oscillator strengths. Our experimental band oscillator strengths are somewhat lower than the expermental values of Lewis et al. (1986) but are in good agreement with the recently calculated values of Friedman (1990).
- Publication:
-
Journal of Geophysical Research
- Pub Date:
- July 1990
- DOI:
- 10.1029/JD095iD08p11743
- Bibcode:
- 1990JGR....9511743Y
- Keywords:
-
- Absorption Cross Sections;
- Earth Atmosphere;
- Oscillator Strengths;
- Oxygen Spectra;
- Schumann-Runge Bands;
- Atmospheric Radiation;
- Electron Transitions;
- Molecular Energy Levels;
- Room Temperature;
- Rotational Spectra;
- Vibrational Spectra;
- Atmospheric Composition and Structure: Middle atmosphere-composition and chemistry