Nucleation in the presence of long-range interactions
Abstract
We present a theory for nucleation at a first-order phase transition where the mediating forces are long range. We find that the long-range force induces cooperative nucleation and growth processes, and that this feedback mechanism produces a well-defined delay time with a sharp onset in the transformation to the stable phase. Closed-form expressions for the characteristic onset time and width of the transition are developed, in good agreement with numerical and existing experimental results.
- Publication:
-
Physical Review A
- Pub Date:
- April 1989
- DOI:
- 10.1103/PhysRevA.39.3672
- Bibcode:
- 1989PhRvA..39.3672C
- Keywords:
-
- Barium Titanates;
- Crystal Growth;
- Ferroelectricity;
- Liquid-Vapor Interfaces;
- Nucleation;
- Phase Transformations;
- Metastable State;
- Phase Diagrams;
- Self Consistent Fields;
- Thermodynamics and Statistical Physics;
- 64.60.Qb;
- 64.60.My;
- Nucleation;
- Metastable phases