Raman spectroscopy study of species responsible for the fast proton conductivity in H 2Sb 4O 11.3H 2O
Abstract
The Raman spectroscopy study of crystallized antimonic acid trihydrate powders in the 20-4000 cm -1 confirme the explicit formula : (H 3O +) 2-x[Sb 4O 11-xOH x] -(2-x).(3+x-2)H 2O. Furthermore it emphasizes the presence of hydrogen bonds between either the SbOSb bridge and H 3O + or the protonated Sb(OH)Sb bridge and H 2O.
- Publication:
-
Journal of Molecular Structure
- Pub Date:
- March 1986
- DOI:
- 10.1016/0022-2860(86)85206-1
- Bibcode:
- 1986JMoSt.143...67H