Chemical composition of venus clouds
Abstract
From estimates of drying effect in the cloud layer, data of the Venera 14 X-ray fluorescent spectroscopy, and evaluation of photochemical production of sulfuric acid, it follows that sulfuric acid and/or products of its further conversion should constitute not only the Mode 2 particles but most of the Mode 3 particles as well. The eddy mixing coefficient equals 2 × 10 4 cm 2 s -1 in the cloud layer. The presence of ferric chloride in the cloud layer is indicated by the Venus u.v. absorption spectrum in the range of 3200-5000 Å, by the Venera 12 X-ray fluorescent spectrum, by the coincidence of the calculated FeCl 3 condensate density profile and that of the Mode 1 in the middle and lower cloud layer, as well as by the upward flux of FeCl 3 from the middle cloud layer which provides the necessary concentration of FeCl 3 in H 2SO 4 solution. FeCl 3 as the second absorber explains the localization of absorption in the upper cloud layer due to the FeCl 3 conversion to ferric sulfate near the boundary between the upper and middle cloud layers. Other possible absorbers such as sulfur, ammonium pyrosulfite, nitrosylsulfuric acid, etc. are discussed.
- Publication:
-
Planetary and Space Science
- Pub Date:
- January 1985
- DOI:
- 10.1016/0032-0633(85)90147-3
- Bibcode:
- 1985P&SS...33..109K
- Keywords:
-
- Atmospheric Chemistry;
- Chemical Composition;
- Venera Satellites;
- Venus Clouds;
- Ammonium Compounds;
- Fluorescence;
- Iron Chlorides;
- Nitrogen Oxides;
- Sulfites;
- Sulfur;
- Sulfuric Acid;
- Ultraviolet Spectra;
- VENUS;
- CLOUDS;
- CHEMISTRY;
- COMPOSITION;
- VENERA 14;
- SPECTROSCOPY;
- LAYERS;
- X-RAY FLUORESCENCE;
- PHOTOCHEMISTRY;
- SULFURIC ACID;
- EDDY EFFECTS;
- MIXING;
- FERRIC CHLORIDE;
- ULTRAVIOLET;
- WAVELENGTHS;
- ABSORPTION;
- SPECTRA;
- FLUX;
- VENERA 12;
- CONDENSATES;
- DENSITY PROFILES;
- CONCENTRATION;
- CALCULATIONS;
- Lunar and Planetary Exploration; Venus