The electronic structure of the one-dimensional tetrahedrally distorted porphyrinatonickel (II) system
Abstract
The band structure of a saddle-shaped porphyrinatonickel (II) backbone is investigated by a semiempirical INDO crystal orbital approach at an interdeck separation of 3.446 Å. The low-dimensional oxidized material (injected holes) belongs to a group of organic metals where Coulomb correlations cannot be neglected in comparison to one-electron tight-binding interactions.
- Publication:
-
Physics Letters A
- Pub Date:
- May 1984
- DOI:
- 10.1016/0375-9601(84)90794-1
- Bibcode:
- 1984PhLA..102..121B