Fused Salt Concentration Cells with Transference. Transport Numbers of Molten (Li, Ag)Cl and Molten Alkali Jodide and Silver Jodide Mixtures
Abstract
The transport numbers of the molten systems (Li.Ag)Cl, (Na.Ag)I, (K,Ag)I, and (Rb,Ag)I have been determined by e.m.f. measurements on concentration cells with transference. With the exception of (Na,Ag)I, for these systems the existence of inversion points (the mobility ratio reverses at a certain mixing ratio) is proven within experimental accuracy. For (Na,Ag)I an inversion point might exist at the high Agl concentration side.
- Publication:
-
Zeitschrift Naturforschung Teil A
- Pub Date:
- August 1983
- DOI:
- 10.1515/zna-1983-0811
- Bibcode:
- 1983ZNatA..38..880R