Etude par resonance quadripolaire des noyaux 63-Cu et 75-As de complexes tetrameres de la triethylarsine avec des halogenures de cuivre(I)

63-Cu and 75-As quadrupole resonance results have been obtained for the tetrameric triethylarsine copper(I) halides (Cl, Br and I). Unusual behaviours of the temperature dependence of the 63-Cu and 75-As quadrupole resonance lines have been observed simultaneously. Between 77 and 300 K, the chlorine derivative undergoes two structural phase changes at 93 and 173 K, while phase transformations occur at 152 and 86 K respectively for the bromine and iodine derivatives.