Elementary Excitations of a Linearly Conjugated Diatomic Polymer
Abstract
The low-lying particlelike excitations of a model linearly conjugated diatomic polymer, (/A=B)/x, are found to be pairs of either spin-0 or spin- 1/2 solitons with irrational charge values. The charge values and excitation energies are calculated as functions of the difference of the energy levels of the atomic p orbitals of the two atomic constitutents of the unit cell. The phonon spectrum of the uniform polymer is also calculated.
- Publication:
-
Physical Review Letters
- Pub Date:
- November 1982
- DOI:
- Bibcode:
- 1982PhRvL..49.1455R
- Keywords:
-
- 72.80.Le;
- 72.15.Nj;
- Polymers;
- organic compounds;
- Collective modes